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(The Mole & Concentrations)

Molar mass, molar volume, mass-volume calculations

Molar Mass, Molar Volume, and Mass-Volume Calculations

Understanding Molar Mass

The molar mass of a substance is the mass of one mole of that substance. It is expressed in grams per mole (g/mol). To find the molar mass, sum the atomic masses of all atoms in a molecule.

For example:

  • The molar mass of water (H2O) is calculated as follows:
    • Hydrogen (H): 2 atoms × 1 g/mol = 2 g/mol
    • Oxygen (O): 1 atom × 16 g/mol = 16 g/mol
    • Total molar mass of H2O = 2 g/mol + 16 g/mol = 18 g/mol

Molar Volume of Gases

At standard temperature and pressure (STP), one mole of any gas occupies a volume of 22.4 liters. This is known as the molar volume of a gas.

For example:

  • 1 mole of carbon dioxide (CO2) at STP occupies 22.4 L.
  • 2 moles of nitrogen gas (N2) at STP occupy 44.8 L.

Mass-Volume Calculations

To calculate the mass or volume of a substance, use the relationships between moles, molar mass, and molar volume.

Steps for Mass-Volume Calculations

  1. Find the number of moles: Use the formula moles=massmolar mass\text{moles} = \frac{\text{mass}}{\text{molar mass}}.
  2. Calculate the volume: For gases at STP, use volume=moles×22.4 L/mol\text{volume} = \text{moles} \times 22.4 \text{ L/mol}.
  3. Calculate the mass: Use mass=moles×molar mass\text{mass} = \text{moles} \times \text{molar mass}.

 

Worked Example

Calculate the volume of 44 g of CO2 at STP.

Tuity Tip

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Remember: Always check if conditions are at STP when using 22.4 L/mol for gases.

Units Matter: Ensure all units are consistent, especially when calculating moles and volume.

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